Strontium SPDF Electron Configuration Explained
Strontium has atomic number 38, meaning it has 38 electrons to arrange across its orbitals. Its ground-state electron configuration is:
Full notation: `1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 5s²`
Shorthand notation: `[Kr] 5s²`
This configuration places Strontium in the S-block of the periodic table — Period 5, Group 2. The last subshell filled (the s subshell) determines its block.
SPDF notation tells you exactly: which subshell each electron occupies, how many electrons are in it, and the energy level of each group. This is far more detail than the simpler Bohr model, which only shows shell totals.
Aufbau Filling Sequence for Strontium
The Aufbau (building-up) principle states electrons fill the lowest available energy subshell first. For Strontium (Z=38), the filling stops at the 5s² subshell.
Standard Aufbau sequence:
1s → 2s → 2p → 3s → 3p → 4s → 3d → 4p → 5s → 4d → 5p → 6s → 4f → 5d → 6p → 7s → 5f → 6d → 7p
After filling, Strontium's configuration ends at 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 5s², with 2 valence electrons in its outermost subshell.
Orbital Diagram of Strontium (s, p, d, f)
The orbital diagram of Strontium expands the configuration 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 5s² into individual orbital boxes:
- Each s subshell holds max 2 electrons (1 orbital)
- Each p subshell holds max 6 electrons (3 orbitals)
- Each d subshell holds max 10 electrons (5 orbitals)
- Each f subshell holds max 14 electrons (7 orbitals)
Hund's Rule dictates that within any subshell, electrons fill each orbital singly (spin up ↑) before pairing. This avoids electron–electron repulsion. Strontium's S-block placement confirms its last orbitals are s type.
The interactive diagram above shows Strontium's complete subshell breakdown with orbital boxes for every energy level.
How to Write Strontium's Electron Configuration
Follow these steps to write Strontium's electron configuration from scratch:
Step 1: Identify the atomic number: Z = 38 — this is the total number of electrons to place.
Step 2: Follow the Aufbau sequence, filling the lowest energy subshells first:
> 1s → 2s → 2p → 3s → 3p → 4s → 3d → 4p → ...
Step 3: Apply Hund's Rule inside each subshell — one electron per orbital before pairing begins.
Step 4: Apply the Pauli Exclusion Principle — each orbital holds at most 2 electrons with opposite spins.
Step 5: After filling all 38 electrons, your result should match:
> 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 5s²
Shorthand: Replace the preceding noble gas core with its symbol:
> [Kr] 5s²
Why Strontium Matters (Real-World Insight)
⚠️ Common Misconception
Common Misconception About Strontium
A frequent error is assuming Strontium always exhibits its primary oxidation state (+2). In reality, Strontium can show different behaviors depending on what it bonds with. Always consider the full context of the reaction.
Valence Electrons & S-Block Position
Strontium has 2 valence electrons — the electrons in its highest occupied principal energy level.
As a S-block element, Strontium's valence electrons reside in s orbitals. These are the only electrons involved in chemical bonding.
| Block | Type | Max Valence e⁻ |
|---|---|---|
| s-block | Groups 1–2 | 1–2 |
| p-block | Groups 13–18 | 3–8 |
| d-block | Groups 3–12 | up to 10 |
| f-block | Lanthanides/Actinides | up to 14 |
Strontium sits in this table as a s-block element with 2 valence electrons.
→ See Strontium's valence electrons in the Bohr model for the shell-based view.
→ Electronegativity of Strontium — how strongly it attracts these electrons.
Frequently Asked Questions
Q. How many electrons does Strontium have?
Strontium has 38 electrons, matching its atomic number. In a neutral atom, these are balanced by 38 protons in the nucleus.
Q. What is the shell structure of Strontium?
The electron shell distribution for Strontium is 2, 8, 18, 8, 2. This shows how all 38 electrons are arranged across 5 principal energy levels.
Q. How many valence electrons does Strontium have?
Strontium has 2 valence electrons in its outermost shell. These are responsible for its chemical bonding and placement in Group 2.
Q. What is the SPDF configuration of Strontium?
The full configuration is 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 5s². This describes the exact subshell occupancy following the Aufbau principle.
Q. What block is Strontium in?
Strontium is in the S-block because its highest-energy electrons occupy s orbitals.

