Nickel SPDF Electron Configuration Explained
Nickel has atomic number 28, meaning it has 28 electrons to arrange across its orbitals. Its ground-state electron configuration is:
Full notation: `1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁸ 4s²`
Shorthand notation: `[Ar] 3d⁸ 4s²`
This configuration places Nickel in the D-block of the periodic table — Period 4, Group 10. The last subshell filled (the d subshell) determines its block.
SPDF notation tells you exactly: which subshell each electron occupies, how many electrons are in it, and the energy level of each group. This is far more detail than the simpler Bohr model, which only shows shell totals.
Aufbau Filling Sequence for Nickel
The Aufbau (building-up) principle states electrons fill the lowest available energy subshell first. For Nickel (Z=28), the filling stops at the 4s² subshell.
Standard Aufbau sequence:
1s → 2s → 2p → 3s → 3p → 4s → 3d → 4p → 5s → 4d → 5p → 6s → 4f → 5d → 6p → 7s → 5f → 6d → 7p
After filling, Nickel's configuration ends at 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁸ 4s², with 10 valence electrons in its outermost subshell. Note: Nickel is a D-block element, so watch for possible Aufbau anomalies driven by extra stability of half-filled or fully-filled d subshells.
Orbital Diagram of Nickel (s, p, d, f)
The orbital diagram of Nickel expands the configuration 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁸ 4s² into individual orbital boxes:
- Each s subshell holds max 2 electrons (1 orbital)
- Each p subshell holds max 6 electrons (3 orbitals)
- Each d subshell holds max 10 electrons (5 orbitals)
- Each f subshell holds max 14 electrons (7 orbitals)
Hund's Rule dictates that within any subshell, electrons fill each orbital singly (spin up ↑) before pairing. This avoids electron–electron repulsion. Nickel's D-block placement confirms its last orbitals are d type.
The interactive diagram above shows Nickel's complete subshell breakdown with orbital boxes for every energy level.
How to Write Nickel's Electron Configuration
Follow these steps to write Nickel's electron configuration from scratch:
Step 1: Identify the atomic number: Z = 28 — this is the total number of electrons to place.
Step 2: Follow the Aufbau sequence, filling the lowest energy subshells first:
> 1s → 2s → 2p → 3s → 3p → 4s → 3d → 4p → ...
Step 3: Apply Hund's Rule inside each subshell — one electron per orbital before pairing begins.
Step 4: Apply the Pauli Exclusion Principle — each orbital holds at most 2 electrons with opposite spins.
Step 5: After filling all 28 electrons, your result should match:
> 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁸ 4s²
Shorthand: Replace the preceding noble gas core with its symbol:
> [Ar] 3d⁸ 4s²
⚠️ Common mistake: Nickel is a d-block element. Verify your d-subshell count carefully — anomalies from expected Aufbau order are possible.
Why Nickel Matters (Real-World Insight)
⚠️ Common Misconception
Common Misconception About Nickel
Students often confuse the electron configuration of Nickel because d-block elements don't always follow the simple Aufbau rule. Nickel's configuration ([Ar] 3d⁸ 4s²) may look unexpected — this is due to the extra stability gained by half-filled or fully-filled d subshells, not an error in the rules.
Valence Electrons & D-Block Position
Nickel has 10 valence electrons — the electrons in its highest occupied principal energy level.
As a D-block element, Nickel's valence electrons reside in d orbitals and d/f orbitals. These are the only electrons involved in chemical bonding.
| Block | Type | Max Valence e⁻ |
|---|---|---|
| s-block | Groups 1–2 | 1–2 |
| p-block | Groups 13–18 | 3–8 |
| d-block | Groups 3–12 | up to 10 |
| f-block | Lanthanides/Actinides | up to 14 |
Nickel sits in this table as a d-block element with 10 valence electrons.
→ See Nickel's valence electrons in the Bohr model for the shell-based view.
→ Electronegativity of Nickel — how strongly it attracts these electrons.
Frequently Asked Questions
Q. How many electrons does Nickel have?
Nickel has 28 electrons, matching its atomic number. In a neutral atom, these are balanced by 28 protons in the nucleus.
Q. What is the shell structure of Nickel?
The electron shell distribution for Nickel is 2, 8, 16, 2. This shows how all 28 electrons are arranged across 4 principal energy levels.
Q. How many valence electrons does Nickel have?
Nickel has 10 valence electrons in its outermost shell. These are responsible for its chemical bonding and placement in Group 10.
Q. What is the SPDF configuration of Nickel?
The full configuration is 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁸ 4s². This describes the exact subshell occupancy following the Aufbau principle.
Q. What block is Nickel in?
Nickel is in the D-block because its highest-energy electrons occupy d orbitals.

