Antimony SPDF Electron Configuration Explained
Antimony has atomic number 51, meaning it has 51 electrons to arrange across its orbitals. Its ground-state electron configuration is:
Full notation: `1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p³`
Shorthand notation: `[Kr] 4d¹⁰ 5s² 5p³`
This configuration places Antimony in the P-block of the periodic table — Period 5, Group 15. The last subshell filled (the p subshell) determines its block.
SPDF notation tells you exactly: which subshell each electron occupies, how many electrons are in it, and the energy level of each group. This is far more detail than the simpler Bohr model, which only shows shell totals.
Aufbau Filling Sequence for Antimony
The Aufbau (building-up) principle states electrons fill the lowest available energy subshell first. For Antimony (Z=51), the filling stops at the 5p³ subshell.
Standard Aufbau sequence:
1s → 2s → 2p → 3s → 3p → 4s → 3d → 4p → 5s → 4d → 5p → 6s → 4f → 5d → 6p → 7s → 5f → 6d → 7p
After filling, Antimony's configuration ends at 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p³, with 5 valence electrons in its outermost subshell.
Orbital Diagram of Antimony (s, p, d, f)
The orbital diagram of Antimony expands the configuration 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p³ into individual orbital boxes:
- Each s subshell holds max 2 electrons (1 orbital)
- Each p subshell holds max 6 electrons (3 orbitals)
- Each d subshell holds max 10 electrons (5 orbitals)
- Each f subshell holds max 14 electrons (7 orbitals)
Hund's Rule dictates that within any subshell, electrons fill each orbital singly (spin up ↑) before pairing. This avoids electron–electron repulsion. Antimony's P-block placement confirms its last orbitals are p type.
The interactive diagram above shows Antimony's complete subshell breakdown with orbital boxes for every energy level.
How to Write Antimony's Electron Configuration
Follow these steps to write Antimony's electron configuration from scratch:
Step 1: Identify the atomic number: Z = 51 — this is the total number of electrons to place.
Step 2: Follow the Aufbau sequence, filling the lowest energy subshells first:
> 1s → 2s → 2p → 3s → 3p → 4s → 3d → 4p → ...
Step 3: Apply Hund's Rule inside each subshell — one electron per orbital before pairing begins.
Step 4: Apply the Pauli Exclusion Principle — each orbital holds at most 2 electrons with opposite spins.
Step 5: After filling all 51 electrons, your result should match:
> 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p³
Shorthand: Replace the preceding noble gas core with its symbol:
> [Kr] 4d¹⁰ 5s² 5p³
Why Antimony Matters (Real-World Insight)
⚡ Reactivity Insight
Antimony's Reactivity — Why It Acts This Way
With 5 electrons in its outer shell, Antimony (Metalloid) has the ability to share electrons when forming bonds. Its ionization energy of 8.608 eV and atomic radius of 133 pm reinforce this pattern, making Antimony a versatile, multi-valent element.
Valence Electrons & P-Block Position
Antimony has 5 valence electrons — the electrons in its highest occupied principal energy level.
As a P-block element, Antimony's valence electrons reside in p orbitals. These are the only electrons involved in chemical bonding.
| Block | Type | Max Valence e⁻ |
|---|---|---|
| s-block | Groups 1–2 | 1–2 |
| p-block | Groups 13–18 | 3–8 |
| d-block | Groups 3–12 | up to 10 |
| f-block | Lanthanides/Actinides | up to 14 |
Antimony sits in this table as a p-block element with 5 valence electrons.
→ See Antimony's valence electrons in the Bohr model for the shell-based view.
→ Electronegativity of Antimony — how strongly it attracts these electrons.
Frequently Asked Questions
Q. How many electrons does Antimony have?
Antimony has 51 electrons, matching its atomic number. In a neutral atom, these are balanced by 51 protons in the nucleus.
Q. What is the shell structure of Antimony?
The electron shell distribution for Antimony is 2, 8, 18, 18, 5. This shows how all 51 electrons are arranged across 5 principal energy levels.
Q. How many valence electrons does Antimony have?
Antimony has 5 valence electrons in its outermost shell. These are responsible for its chemical bonding and placement in Group 15.
Q. What is the SPDF configuration of Antimony?
The full configuration is 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p³. This describes the exact subshell occupancy following the Aufbau principle.
Q. What block is Antimony in?
Antimony is in the P-block because its highest-energy electrons occupy p orbitals.

